The physical properties of alkene-terminated liquid crystal molecules/E8 mixture and the electro-optical properties as they doped in polymer-dispersed liquid crystal systems
机构:[1]Department of Materials, University of Science and Technology Beijing, Beijing, P. R. China[2]Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing, P. R. China[3]Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Peking University, Beijing, P. R. China[4]The Middle School Affiliated to Beijing Jiaotong University, Beijing, P. R. China[5]Beijing Tongren Eye Center, Capital Medical University, Beijing, P. R. China首都医科大学附属北京同仁医院首都医科大学附属同仁医院
Effects of the content of fluorinated alkene-terminated liquid crystal (LC) molecules on the physical properties of the fluorinated alkene-terminated LC/E8 mixture were studied. The morphology and electro-optical properties as they doped in polymer-dispersed liquid crystal (PDLC) films were investigated. The detailed discussion of the obtained results is given. As a result, comparing with the physical properties of the series of LC mixtures with the same content of the analogous fully saturated compounds doped with E8, we find that the birefringence is significantly larger for the LC mixture with the alkene-terminated materials. Both fluorinated alkene-terminated LC molecules and the analogous fully saturated compounds doped with E8 reduce the driving voltage of PDLC films. Moreover, PDLC films with the fluorinated alkene-terminated LC molecules possessed higher contrast ratio and faster response time than that of the PDLC films prepared by adding the same mass fraction of the analogous fully saturated compounds. Thus, the ability to manipulate physical properties of LC mixture and electro-optical properties of PDLC films by changing the LC molecular structures may have future relevance for new LC structures design and applications of PDLC films. [GRAPHICS]
基金:
This work was supported by the National Natural Science
Foundation of China [Grant numbers 8200902864,
51573101, 8200902976, 51773017, 51473020]; the
Fundamental Research Funds for the Central Universities
[Grant number FRF-GF-17-B8].
第一作者机构:[1]Department of Materials, University of Science and Technology Beijing, Beijing, P. R. China
通讯作者:
通讯机构:[1]Department of Materials, University of Science and Technology Beijing, Beijing, P. R. China[2]Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing, P. R. China[3]Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Peking University, Beijing, P. R. China[5]Beijing Tongren Eye Center, Capital Medical University, Beijing, P. R. China
推荐引用方式(GB/T 7714):
Zhang Huimin,Zhong Tingjun,Chen Mei,et al.The physical properties of alkene-terminated liquid crystal molecules/E8 mixture and the electro-optical properties as they doped in polymer-dispersed liquid crystal systems[J].LIQUID CRYSTALS.2018,45(8):1118-1128.doi:10.1080/02678292.2017.1411984.
APA:
Zhang, Huimin,Zhong, Tingjun,Chen, Mei,Zhang, Lanying,Liu, Xing...&Zhu, Siquan.(2018).The physical properties of alkene-terminated liquid crystal molecules/E8 mixture and the electro-optical properties as they doped in polymer-dispersed liquid crystal systems.LIQUID CRYSTALS,45,(8)
MLA:
Zhang, Huimin,et al."The physical properties of alkene-terminated liquid crystal molecules/E8 mixture and the electro-optical properties as they doped in polymer-dispersed liquid crystal systems".LIQUID CRYSTALS 45..8(2018):1118-1128