机构：[1]Department of Materials Physics and Chemistry, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing, People’s Republic of China[2]Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing, People’s Republic of China[3]Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Peking University, Beijing, People’s Republic of China[4]School of Science, Xijing University, Xi’an, Shaanxi Province, People’s Republic of China[5]College of Medical Laboratory, Dalian Medical University, Dalian, Liaoning Province, People’s Republic of China[6]The Experimental High School Attached To Beijing Normal University, Beijing, People’s Republic of China[7]Beijing Tongren Hospital, CMU, Beijing, People’s Republic of China首都医科大学附属北京同仁医院首都医科大学附属同仁医院
To study effects of the crosslinking agent/diluents/thiol on morphology of the polymer matrix and the electro-optical properties of polymer-dispersed liquid crystal (PDLC) films, samples were prepared by ultraviolet (UV)-initiated polymerisation. Due to the interaction between thiol-acrylate reaction and acrylate monomers polymerisation, the sample compositions were the foremost determinant to the microstructures which in turn played an essential role on the electro-optical properties of the PDLC films. With the increasing content of the crosslinking agent, the LC droplet size decreased, while the thiol had a contrary effect on the LC droplet size. It was demonstrated that the superior properties of the low-driven voltage (37.2V), the high contrast ratio (148.2), the short response time (14.9ms) and the high saturation transmittance (86.6%) could benefit from a novel microstructure which had a dense surface and meshes with microspheres attached. It was of great significance for the optimisation and the potential applications of the PDLC films. [GRAPHICS] .
基金：
National Natural Science
Foundation of China (Grant No. 51673023, 51373024,
51573003, 51333001 and 51372029).
第一作者机构：[1]Department of Materials Physics and Chemistry, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing, People’s Republic of China
通讯作者：
通讯机构：[1]Department of Materials Physics and Chemistry, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing, People’s Republic of China[2]Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing, People’s Republic of China[3]Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Peking University, Beijing, People’s Republic of China
推荐引用方式(GB/T 7714)：
Zhang Yi,Zhou Le,Yang Jie,et al.Effects of crosslinking agent/diluents/thiol on morphology of the polymer matrix and electro-optical properties of polymer-dispersed liquid crystal[J].LIQUID CRYSTALS.2018,45(5):728-735.doi:10.1080/02678292.2017.1376716.
APA：
Zhang, Yi,Zhou, Le,Yang, Jie,Zhang, Jiazhen,Hai, Mingtan...&Zhu, Siquan.(2018).Effects of crosslinking agent/diluents/thiol on morphology of the polymer matrix and electro-optical properties of polymer-dispersed liquid crystal.LIQUID CRYSTALS,45,(5)
MLA：
Zhang, Yi,et al."Effects of crosslinking agent/diluents/thiol on morphology of the polymer matrix and electro-optical properties of polymer-dispersed liquid crystal".LIQUID CRYSTALS 45..5(2018):728-735
